Monday, 01 February 2021
Using salt as a key ingredient, Chinese and British researchers have designed a new type of rechargeable battery that could accelerate the shift to greener, electric transport on our roads.
Many electric vehicles (EV) are powered by rechargeable lithium-ion batteries, but they can lose energy and power over time. Under certain conditions, such batteries can also overheat while working or charging, which can also degrade battery life and reduce miles per charge.
To solve these issues, the University of Nottingham is collaborating with six scientific research institutes across China to develop an innovative and affordable energy store with the combined performance merits of a solid-oxide fuel cell and a metal-air battery. The new battery could significantly extend the range of electric vehicles, while being fully recyclable, environmentally-friendly, low-cost and safe.
A solid-oxide fuel cell converts hydrogen and oxygen into electricity as a result of a chemical reaction. While they are highly-efficient at extracting energy from a fuel, durable, low-cost and greener to produce, they are not rechargeable. Meanwhile, metal-air batteries are electrochemical cells that uses a cheap metal such as iron and the oxygen present in air to generate electricity. During charging, they emit only oxygen into the atmosphere. Although not very durable, these high-energy dense batteries are rechargeable and can store and discharge as much electricity as lithium-ion batteries, but much more safely and cheaply.
In the early research phases, the research team explored a high-temperature, iron-air battery design that used molten salt as a type of electrolyte - activated by heat - for electrical conductivity. Cheap and inflammable, molten salts help to give a battery impressive energy storage and power capability and a lengthy lifecycle.
However, molten salts also possess adverse characteristics.
“In extreme heat, molten salt can be aggressively corrosive, volatile and evaporate or leak, which is challenging to the safety and stability of battery design. There was an urgent need to fine-tune these electrolyte characteristics for better battery performance and to enable its future use in electric transport.”
A quasi-solid-state (QSS) molten salt electrolyte and the structure of QSS molten salt iron air battery
The researchers have now successfully improved the technology by turning the molten salt into soft-solid salt, using solid oxide nano-powders. Professor Jianqiang Wang, from the Shanghai Institute of Applied Physics, Chinese Academy of Sciences, who is leading this collaboration project has predicted that this quasi-solid-state (QSS) electrolyte is suitable for metal-air batteries which operate at 800 ºC - about the same as that of the engine exhaust gas from a petrol or diesel engine - as it suppresses the evaporation and fluidity of the molten salts that can occur at such high operating temperatures.
In principle, maintaining an effective working temperature can be achieved by the currents for charging and discharging of the battery, good thermal insulation, and some additional electric heating if necessary.
Project collaborator, Dr Cheng Peng, also from the Shanghai Institute of Applied Physics, Chinese Academy of Sciences, explains a unique and useful design aspect of this experimental research. The quasi-solidification has been achieved using nanotechnology to construct a flexibly-connected network of solid oxide particles that act as a structural barrier locking in the molten salt electrolytes, while still allowing them to safely conduct electricity in extreme heat.
Professor Chen, who is leading a molten salt electrolysis laboratory in Nottingham, hopes the team’s “encouraging results” will help to establish a simpler and more efficient approach to designing low-cost and high-performance molten salt metal-air batteries with high stability and safety.
He adds, “The modified molten salt iron-oxygen battery has great potential applications in new markets, including electric transport and renewable energy which require innovative storage solutions in our homes and at grid-level. The battery is also, in principle, capable of storing solar heat as well as electricity, which is highly-desirable for both domestic and industrial energy needs. Molten salts are currently used at large scale in Spain and China to capture and store solar heat which is then converted to electricity - our molten salt metal air battery does the two jobs in one device.”
The full article, ‘Quasi-solid-state electrolyte for rechargeable high-temperature molten salt iron-air battery’, outlining the results, is published in the journal Energy Storage Materials.
Story credits
More information is available from Professor George Chen, Professor of Electrochemical Technologies in the Faculty of Engineering on +44 (0) 1159514171 or George.chen@nottingham.ac.uk or Emma Lowry, Media Relations Manager (Engineering) on 0115 84 67156 or emma.lowry@nottingham.ac.uk
Notes to editors:
About the University of Nottingham
Ranked 32 in Europe and 16th in the UK by the QS World University Rankings: Europe 2024, the University of Nottingham is a founding member of the Russell Group of research-intensive universities. Studying at the University of Nottingham is a life-changing experience, and we pride ourselves on unlocking the potential of our students. We have a pioneering spirit, expressed in the vision of our founder Sir Jesse Boot, which has seen us lead the way in establishing campuses in China and Malaysia - part of a globally connected network of education, research and industrial engagement.
Nottingham was crowned Sports University of the Year by The Times and Sunday Times Good University Guide 2024 – the third time it has been given the honour since 2018 – and by the Daily Mail University Guide 2024.
The university is among the best universities in the UK for the strength of our research, positioned seventh for research power in the UK according to REF 2021. The birthplace of discoveries such as MRI and ibuprofen, our innovations transform lives and tackle global problems such as sustainable food supplies, ending modern slavery, developing greener transport, and reducing reliance on fossil fuels.
The university is a major employer and industry partner - locally and globally - and our graduates are the second most targeted by the UK's top employers, according to The Graduate Market in 2022 report by High Fliers Research.
We lead the Universities for Nottingham initiative, in partnership with Nottingham Trent University, a pioneering collaboration between the city’s two world-class institutions to improve levels of prosperity, opportunity, sustainability, health and wellbeing for residents in the city and region we are proud to call home.
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